EHS
OSHA / NIOSH Chemical Exposure & PPE Engine

Octane

CAS: 111-65-9
•
RTECS: N/A
OSHA PEL (8-hr TWA) 500 ppm OSHA PEL: 500 ppm / 2350 mg/m3
NIOSH REL 75 ppm NIOSH REL: 75 ppm(C) 385 ppm [15-min]
IDLH Threshold 5000 ppm Imm. Dangerous to Life/Health
Skin Hazard Notation No Dermal standard 29 CFR 1910
Interactive Engine

Octane Shift Exposure & PPE Compliance Calculator

Input your measured workplace air sample concentration and work shift schedule. The engine applies the Brief & Scala mathematical reduction model to determine legally defensible compliance.

ppm
OSHA Compliance Determination Awaiting Sample Input
Adjusted PEL (Brief-Scala)
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Hazard Ratio (HR)
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Mandated APF Respirator
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Enter an air sampling concentration above to evaluate whether your facility triggers the OSHA Action Level (0.5× PEL) or requires mandatory respiratory protection under 29 CFR 1910.134.

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Generates an instant 1-page OSHA 29 CFR 1910.1000 compliance record.

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NIOSH Respirator & Barrier Protection Specifications

Required Cartridge / Filter Organic Vapor (Black)

Certified for concentrations within permissible limits.

Chemical Barrier Gloves Nitrile or Neoprene Chemical Barrier

Prevents transdermal permeation.

NIOSH Respiratory Protocol:

Mandatory NIOSH-approved Organic Vapor (Black) required when airborne concentration exceeds action level under OSHA 29 CFR 1910.134.

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Frequently Asked Questions About Octane Exposure

What is the legal OSHA PEL for Octane?

Under OSHA 29 CFR 1910.1000 Table Z-1, the 8-hour Time-Weighted Average (TWA) Permissible Exposure Limit (PEL) for Octane (CAS 111-65-9) is 500 ppm. In addition, NIOSH recommends a Recommended Exposure Limit (REL) of 75 ppm.

How do extended 10-hour and 12-hour shifts affect Octane exposure limits?

Because OSHA PELs are formulated for 8-hour workdays, working 10-hour or 12-hour shifts reduces recovery time. Applying the standard Brief & Scala mathematical model reduces the allowable concentration by a Reduction Factor (RF = 0.700 for 10-hr, RF = 0.500 for 12-hr). For Octane, an 8-hr PEL of 500 ppm adjusts to half that value on a 12-hour shift.

What respirator and PPE is required when handling Octane?

When atmospheric concentrations exceed the permissible limit up to 10× PEL, OSHA 29 CFR 1910.134 mandates a half-mask elastomeric respirator equipped with Organic Vapor (Black). For dermal exposure, Nitrile or Neoprene Chemical Barrier are recommended.

What is the IDLH threshold for Octane?

The Immediately Dangerous to Life or Health (IDLH) concentration established by NIOSH for Octane is 5000 ppm. Any entry into atmospheres at or above this concentration requires positive-pressure supplied air or Self-Contained Breathing Apparatus (SCBA).

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